A Plastic Revolution – Dissolves in Seawater and Degrades in Soil Within 10 Days

 November 28th, 2024

By Lily Anderson

Staff Writer for Wake Up World

Plastic pollution has long plagued our planet, with microplastics infiltrating oceans, soil, and even our bodies. But a groundbreaking discovery by researchers at the RIKEN Center for Emergent Matter Science (CEMS) offers hope. Led by Takuzo Aida, the team has developed a new type of plastic that’s not only durable and recyclable but also fully ocean-degradable. This innovation could significantly reduce microplastic pollution and reshape how we think about plastic use.

The Plastic Problem

Conventional plastics, though versatile and durable, come with a heavy environmental cost. Their resistance to degradation means they persist for centuries, breaking down into harmful microplastics—tiny fragments less than 5 millimeters in size. These microplastics pollute ecosystems, harm marine life, and eventually make their way into the food chain, posing health risks to humans.

Even biodegradable plastics like PLA, commonly used as alternatives, fall short. While they degrade in industrial composting conditions, they often fail to break down in ocean environments, where water insolubility remains a significant challenge.

As Aida’s team highlights, “The key issue with existing biodegradable plastics is their inability to degrade effectively in seawater, where much of the pollution ends up.” Addressing this gap, the researchers focused on creating a material that dissolves specifically in salt water, ensuring it leaves no harmful traces.

A New Era in Plastic: Supramolecular Innovation

The breakthrough material is a supramolecular plastic, a type of polymer held together by reversible interactions. By combining two ionic monomers, the team created cross-linked salt bridges that give the plastic its strength and flexibility.

One of the monomers, sodium hexametaphosphate, is a common food additive, while the other is a guanidinium ion-based monomer. Both components are biodegradable and can be metabolized by bacteria once the plastic dissolves.

Aida explains, “While the reversible nature of bonds in supramolecular plastics was thought to make them weak, our material is just the opposite. The salt bridges remain stable until exposed to seawater, where electrolytes trigger their breakdown.”

The Critical “Desalting” Step

The manufacturing process was pivotal. When the monomers were mixed in water, the reaction produced two layers: a thick, viscous liquid containing the salt bridges and a watery layer with expelled salt ions. Drying the thick layer resulted in durable plastic, while skipping this step left behind brittle crystals.

Once formed, the plastic, dubbed alkyl SP2, proved to be strong, non-toxic, and customizable. It could be reshaped at high temperatures and tailored to meet various needs, from hard, scratch-resistant materials to flexible, rubber-like plastics.

A Sustainable Solution: Recyclable and Biodegradable

The team also prioritized recyclability and biodegradability. When exposed to salt water, the plastic’s structure destabilized, dissolving into its original monomer components. The researchers recovered over 90% of the sodium hexametaphosphate and 82% of the guanidinium, making the recycling process efficient and sustainable.

In soil tests, the plastic degraded completely within 10 days, enriching the earth with phosphorus and nitrogen, much like a fertilizer. This rapid breakdown ensures that no microplastics are left behind.

“With this new material, we’ve created a family of plastics that are strong, stable, recyclable, and, importantly, do not generate microplastics,” Aida states.

A Versatile Future for Plastic

The potential applications of this material are vast. From everyday items like packaging to advanced uses in 3D printing and healthcare, the plastic’s customizable properties make it a game-changer. Its non-flammable nature also means it doesn’t emit harmful CO2 when reshaped, further reducing its environmental footprint.

One particularly exciting development involves ocean-degradable plastics made from polysaccharides. These materials could revolutionize industries reliant on single-use plastics, offering a sustainable alternative that dissolves harmlessly in seawater.

The Road Ahead

While the innovation is promising, scaling production and integrating this material into mainstream use will be critical. Policymakers, industries, and consumers must work together to prioritize sustainable alternatives over conventional plastics. With further research and widespread adoption, we may finally reverse plastic pollution.

For now, Aida’s team has paved the way for a cleaner, healthier planet. Their work reminds us that progress is possible when innovation and sustainability go hand in hand.

Journal Reference:

  1. Mechanically strong yet metabolizable supramolecular plastics by desalting upon phase separation. Science, 2024; 386 (6724): 875 DOI: 10.1126/science.ado1782
  2. Bye-bye microplastics: New plastic is recyclable and fully ocean-degradable – sciencedaily.com/releases/2024/11/241121141011

About the Author

Lily Anderson is an enthusiastic writer and curious investigator of the latest scientific developments. Driven by a strong desire to learn, she has a knack for simplifying complex concepts into engaging stories, making science accessible and interesting to a broad audience. Lily’s work is important for connecting specialists with the general public, sparking wonder, and fostering meaningful conversations about new scientific discoveries.


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